Buchwald Group - 2001-2002 Research Publications

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2002

SLB #	Authors	Title	Journal Reference
215.	Rutherford, J. L.; Rainka, M. P.; Buchwald, S. L.	An Annulative Approach to Highly Substituted Indoles: Unusual Effect of Phenolic Additives on the Success of the Arylation of Ketone Enolates	J. Am. Chem. Soc. 2002, 124, 15168-15169
214.	Klapars, A.; Buchwald, S. L.	Copper-Catalyzed Halogen Exchange in Aryl Halides: An Aromatic Finkelstein Reaction	J. Am. Chem. Soc. 2002, 124, 14844-14845
213.	Singh, U. K.; Strieter, E. R.; Blackmond, D. G.; Buchwald, S. L.	Mechanistic Insights into the Pd(BINAP)-Catalyzed Amination of Aryl Bromides: Kinetic Studies under Synthetically Relevant Conditions	J. Am. Chem. Soc. 2002, 124, 14104-14114
212.	Job, G. E.; Buchwald, S. L.	Copper-Catalyzed Arylation of b-Amino Alcohols	Org. Lett. 2002, 4, 3703-3706
211.	Kwong, F. Y.; Buchwald, S. L.	A General, Efficient, and Inexpensive Catalyst System for the Coupling of Aryl Iodides and Thiols	Org. Lett. 2002, 4, 3517-3520
210.	Antilla, J. C.; Klapars, A.; Buchwald, S. L.	The Copper-Catalyzed N-Arylation of Indoles	J. Am. Chem. Soc. 2002, 124, 11684-11688
209.	Spielvogel, D. J.; Davis, W. M.; Buchwald, S. L.	Preparation, Crystal Structure Analysis, and Catalytic Application of [(S)-BINAP]Ni(COD) and [(S)-BINAP]NiBr2	Organometallics 2002, 21, 3833-3836
208.	Harris, M. C.; Huang, X.; Buchwald, S. L.	Improved Functional Group Compatibility in the Palladium-Catalyzed Synthesis of Aryl Halides	Org. Lett. 2002, 4, 2885-2888
207.	Klapars, A.; Antilla, J.; Huang, X.; Buchwald, S. L.	A General and Efficient Copper Catalyst for the Amidation of Aryl Halides	J. Am. Chem. Soc. 2002, 124, 7421-7428
206.	Yin, J.; Buchwald, S.L.	The Pd-Catalyzed Intermolecular Amidation of Aryl Halides: The Discovery that Xantphos can be Trans-Chelating in a Palladium Complex	J. Am. Chem. Soc. 2002, 124, 6043-6048
205.	Sturla, S.J.; Buchwald, S. L.	Cobalt-Phosphite-Catalyzed Asymmetric Pauson-Khand Reaction	J. Org. Chem. 2002, 67, 3398-3403
204.	Spielvogel, D.; Buchwald, S. L.	Nickel-BINAP Catalyzed Enantioselective α-Arylation of α-Substituted γ-Butyrolactones	J. Am. Chem. Soc. 2002, 124, 3500-3501
203.	Jurkauskas, V; Buchwald, S.L.	Dynamic Kinetic Resolution via Asymmetric Conjugate Reduction: Enantio- and Diastereoselective Synthesis of 2,4-Dialkyl Cyclopentones	J. Am. Chem. Soc. 2002, 124, 2892-2893
202.	Hamada, T.; Buchwald, S.L.	P-Chirogenic Binapthyl-Substituted Monophosphines: Synthesis and Use in EnolateVinylation/Arylation Reactions	Org. Lett. 2002, 4, 999-1001
201.	Wolter, M; Nordmann, G; Job, G.E.; Buchwald, S.L.	Copper-Catalyzed Coupling of Aryl Iodides with Aliphatic Alcohols	Org. Lett. 2002, 4, 973-976
200.	Kwong, F.Y.; Klapars, A.; Buchwald, S.L.	The Copper-Catalyzed Coupling of Alkyl Amines and Aryl Iodides: An Efficient System Even in an Air Atmosphere	Org. Lett. 2002, 4, 581
199.	Hennessy, E.J.; Buchwald, S.L.	A General and Mild Copper-Catalyzed Arylation of Diethyl Malonate	Org. Lett. 2002, 4, 269
198.	Yin, J.; Rainka, M.P.; Zhang X.-X.; Buchwald, S.L.	A Highly Active Suzuki Catalyst for the Synthesis of Sterically Hindered Biaryls: Novel Ligand Coordination	J. Am. Chem. Soc. 2002, 124, 1162
197.	Sturla, S.J.; Buchwald, S.L.	Monocyclopentadienyltitanium Aryloxide Complexes: Preparation, Characterization, and Application in Cyclization Reactions	Organometallics 2002, 21, 739
196.	Gaertzen, O.; Buchwald, S.L.	Palladium-Catalyzed Intramolecular α-Arylation of α-Amino Acid Esters	J. Org. Chem. 2002, 67, 465
195.	Hamada, T; Chieffi, A.; Åhman, J.; Buchwald, S.L.	An Improved Catalyst for the Asymmetric Arylation of Ketone Enolates	J. Am. Chem. Soc. 2002, 124, 1261
193.	Vogl, E.M.; Buchwald, S.L.	The Palladium-Catalyzed Monoarylation of Nitroalkanes	J. Org. Chem. 2002, 67, 106

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2001

SLB #	Authors	Title	Journal Reference
194.	Kuwabe, S.-I.; Torraca, K.E.; Buchwald, S.L.	Palladium-Catalyzed Intramolecular C-O Bond Formation	J. Am. Chem. Soc. 2001, 123, 12202
192.	Wolter, M.; Klapars, A.; Buchwald, S.L.	Synthesis of N-Aryl Hydrazides by Copper-Catalyzed Coupling of Hydrazides with Aryl Iodides	Org. Lett. 2001,3, 3803
191.	Huang, X.; Buchwald, S.L.	New Ammonia Equivalents for the Pd-Catalyzed Amination of Aryl Halides	Org. Lett. 2001,3, 3417
190.	Torraca, K.E.; Xuang, H.; Parrish, C.A.; Buchwald, S.L.	An Efficient Intermolecular Palladium-Catalyzed Synthesis of Aryl Ethers	J. Am. Chem. Soc. 2001, 123, 10770
189.	Kaye, S.; Fox, J.M.; Hicks, F.A.; Buchwald, S.L.	The Use of Catalytic Amounts of CuCl and Other Improvements in the Benzyne Route to Biphenyl-Based Phosphine Ligands	Adv.Syn. Cat., 2001, 8, 789
187.	Klapars, A.; Antilla, J.; Huang, X.; Buchwald, S.L.	A General and Efficient Copper Catalyst for the Amidation of Aryl Halides and the N-Arylation of Nitrogen Heterocycles	J. Am. Chem. Soc. 2001, 123, 7727
186.	Moradi, W.; Buchwald, S.L.	Palladium-Catalyzed α-Arylation of Esters	J. Am. Chem. Soc. 2001, 123, 7996
185.	Zhang, X.-X.; Harris, M.C.; Sadighi, J.P.; Buchwald, S.L.	The Use of Palladium Chloride as a Precatalyst for the Amination of Aryl Bromides	Can. J. Chem., 2001, 79, 1799
184.	Antilla, J.; Buchwald, S.L.	Copper-Catalyzed Coupling of Arylboronic Acids and Amines	Org. Lett. 2001, 3, 2077
183.	Chieffi, A.; Kamikawa, K.; Åhman, J.; Fox, J.M.; Buchwald, S.L.	Catalytic Asymmetric Vinylation of Ketone Enolates	Org. Lett. 2001, 3, 1897
182.	Parrish, C.A.; Buchwald, S.L.	Use of Polymer-Supported Dialkylphosphinobiphenyl Ligands for Palladium-Catalyzed Amination and Suzuki Reactions	J. Org. Chem. 2001, 66, 3820
181.	Yun, J.; Buchwald, S.L.	One-pot Synthesis of Enantiomerically Enriched 2,3-Disubstituted Cyclopentanones via Copper-Catalyzed 1,4-Reduction and Alkylation	Org. Lett. 2001, 3, 1129
180.	Parrish, C.A.; Buchwald, S.L.	Palladium-Catalyzed Formation of Aryl tert-butyl Ethers from Unactivated Aryl Halides	J. Org. Chem. 2001, 66, 2498
179.	Ali, M.; Buchwald, S.L.	An Improved Method for the Palladium-Catalyzed Amination of Aryl Iodides	J. Org. Chem. 2001, 66, 2560